As a part of the SEESIMA workshop in Apatity a study visit was arranged to the Phosagro processing plant at Khibny – the world’s largest producer of high-grade phosphate ore (P2O5 content 39%) – phosphate rock and Russia’s only producer of nepheline concentrate.
A SEESIMA project workshop was held in Apatity, Kola Peninsula on 20th November 2019. The results from the first 10 months of the Kolarctic CBC SEESIMA project were presented and discussed. Twenty five researchers involved in the project were present at the meeting hosted by the Mining Institute of the Kola Science Centre of the Russian Academy of Science.
The meeting was opened with a presentation from Galina Nikolaeva, from the Ministry of Investment, Enterprise Development and Fisheries, Department of Industrial Development and Investment project support, Murmansk. The presentation highlighted the importance of mining to the economic and social development of North-West Russia.
The SEESIMA project results will be progressively presented here on the SEESIMA webpage.
Project activities from the first included
- Literature review of energy saving technologies for dry and wet grinding and different types of stirred-media mills.
- Utilisation of mining waste for production of building materials.
- Improvement of process flowsheets for iron ores, including multi-stage extraction of the concentrate.
- Sorption of heavy metal ions from mining waste water with organic and inorganic sorbents, and handling of spet sorption materials
- Microbial reduction of sulphate in mining waste water
- Extraction of Rare Earth Elements from apatite/phosphate concentrates, and from tailings, with a new technique and methods for handling radionuclides.
- Preparation of functional titanium compounds from apatite-nepheline waste.
- Development of a flotation technique for recovering copper and nickel from historical tailings.
- Development of geotechnical barriers from mining waste materials.
A seminar/workshop is to be held at Kjeøy Research and Education Centre in Vestbygd in Northern Norway. This will involve introductory presentations by specialists in the field of metal leaching from minerals, as well as time for discussion of both microbial and chemical leaching processes. Environmental aspects of natural leaching in cold climates will also be covered. Further details about the seminar, and registration information is available here.
A rather negatively-oriented article recently highlighted the developments in the Rare Earth Mineral industry in China. Unfortunately the article is rather light on technical details, choosing to highlight the environmental impacts. According to the article there have been many ‘pirate’ operations extracting Rare Earth Elements (REE), and extraction techniques include in situ leaching where chemicals are pumped into soil to dissolve and extract the elements from the soil. It is mentioned that other extraction techniques are in use and under development with lower impacts.
As posted earlier, LKAB in Sweden is studying the recovery of REE from iron ore tailings, and NW Russia have existing commercial operations doing this. The waste chemical mentioned in the article on China, “ammoniacal nitrogen” sounds like a potential resource for fertiliser production, or at least can be treated in an analogous manner to the treatment of sulphate in mining waste water being studied in the SEESIMA project WP5.
An article with more technical detail on the Chinese REE industry can be found here, This article focuses on the ion absorption type of REE deposits, which are only found in China. Although only representing less than 3% of China’s REE deposits, they have a higher content of medium and heavy REE and simpler extraction, being easily extracted by ion exchange with ammonium sulphate solutions. This is the basis for the in situ leaching processes, which avoided the environmental impact of open excavation.
Breakdown of sulphur-containing minerals often results in the release of sulphate (such as with acid mine drainage). One way to combat the environmental problems that this causes is to use certain types of bacteria that reduce the sulphate back to sulphur or sulphide compounds.
Sulphate reduction and metal sulphide removal experiments are going on at the University of Oulu. Sulphate reducing bacteria are cultivated in bottle scale and tested for utilization of KemiCond treated sewage sludge and succinate. At the same time synthetic mining water is treated, and iron is recovered as FeS. Furthermore, tests with other low-cost carbon sources and real mining waters, as well as reactor experiments are planned to be started in the autumn 2019.
For more details, contact Hanna Virpiranta
An EU EIT Raw Materials project is developing a “briefcase” of resource material for school teachers to introduce the importance of minerals for society.
The Briefcase project brings the opportunity to learn more about minerals through hands-on experience. The specific target audience will be primary schools which include from 6 to 14-year-old students and their teachers. The project is orientated for Wider Society Learning (WSL) and aims to raise students’ knowledge of mining activities and mineral applications.
The aim of the project is to raise awareness of minerals knowledge among children during their visits to the museum. A real briefcase that contains minerals and products was created in 2003 to help students recognise mineral ores and their uses in daily life.
Read more here
Recently a new EU innovation project was launched, with funding from EIT Raw Materials and project partners from Slovakia, Italy, Hungary, Spain, Germany, Poland, Portugal and Ireland. The project is led by Dr Darina Štyriaková, of the Faculty of Mining, Ecology, Process Control and Geotechnologies of the Technical University of Košice in Slovakia. The aim of the project is to develop biotechnologies to achieve ecological exploitation, improve the quality of local minerals and reduce the European countries’ dependence on imported minerals. More details about the project can be found here:
In February 2019 Dr. Tiina Leiviskä and MSc. Hanna Virpiranta visited Prof. David Barrie Johnson’s group Bangor Acidophile Research Team (BART) in Bangor University, Wales, UK. Hanna stayed there for two weeks working alongside with other visiting and post-doctoral researchers of the team. She acquired a lot of knowledge of e.g. operating sulfate-reducing bioreactors, plating of anaerobic microbes, and conducting bioleaching experiments, that she can exploit in her further research.
LKAB are planning to invest 45 million kronor in pilot plants for recovery of phosphorus and Rare Earth Minerals (REE) from the waste rock from their iron ore mining operation. This development was announced on 20 February 2019, read more here
The pilot plant trial is based on the CleanMAP process developed by Easy Mining, a daughter company of the waste treatment company RagnSells. Details of the CleanMAP process are given here. This seems to be based on the US Patent 8658117 B2, which however only refers to “known processes” for the digestion of apatite with sulfuric acid, hence presumably the traditional use of concentrated sulfuric acid. This patent does not mention the procedure for separation and purification of the rare earth elements. An example of a method to recover rare earth elements from digestion of apatite with strong acid is given in the patent by Genkin et al US 1001 1891.